Contenu

Emballages et contenants Industrie
The Practical Guide to Surface Science (2026)

?s=100&d=m
Écrit par
No biography added yet.
Lire la suite
?s=100&d=m
Reviewed by
N/A
No biography added yet.
Lire la suite
?s=100&d=m
Written By

No biography added yet.

?s=100&d=m
Évalué par

N/A N/A

No biography added yet.

This is a practical guide to Surface Science for researchers working in the Packaging and Containers Industry.

Dans ce tout nouveau guide, vous apprendrez tout sur :

  • Crucial surface science principles
  • The significance of surface science measurements for the Packaging and Containers industry
  • Normes et directives ASTM applicables

Plongeons dans le vif du sujet.

packaging containers

Executive Summary

What it covers: A practical surface-science guide for packaging and container teams covering contact angle (static + advancing/receding), surface tension (static + dynamic), surface energy, and sliding angle—and how each measurement connects to packaging performance. It ties these measurements to real packaging problems like oil/grease resistance, moisture sensitivity of bio-films, leak risk, ink removal for recycling, and label adhesion on curved packs.
Key insights: For real packaging surfaces (porous papers, coated films, treated plastics), single “static” angles can be misleading—dynamic advancing/receding angles and time-stamped measurements better capture hysteresis, roughness, contamination, and absorption effects. Use Young–Laplace fitting for more consistent droplet-shape analysis when axisymmetry holds, and use dynamic surface tension when fast interface changes drive outcomes (dispensing, foaming, wetting/leveling, drying/coating).
Business value: Better control of wettability and interfacial behavior improves coating holdout, grease/water resistance, print quality, and adhesive/label performance—reducing scrap, customer complaints, and line downtime. Surface measurements also support circularity goals by improving de-inking/cleaning performance in mechanical recycling and accelerating development of compostable or bio-based packaging films with predictable moisture behavior.
Standards to follow: Follow TAPPI T 458 / ASTM D724 for porous paper and paperboard wettability using fixed-time (time-stamped) angle-of-contact reporting for sizing and holdout QC. For broader, reproducible wettability/SFE workflows and dynamic angles/roll-off behavior, align methods with the ISO 19403 series, and document controlled conditioning, timestamps, and pass/fail data-quality rules to keep QC trending comparable.
Bottom line: This is a practical, packaging-focused playbook for choosing the right surface measurement, running it in a repeatable way, and translating the numbers into decisions that improve barrier performance, print/recycle outcomes, and adhesion—while supporting sustainability-driven material shifts. It helps teams move from trial-and-error to measurable, spec-driven surface control across paper, films, coatings, and finished packs.

Chapitre 1 : Introduction

In today’s packaging and container industry, success is determined by factors such as product quality, user experience, and environmental impact. This can be illustrated through a simple yet detailed example: oil and grease-resistant paper, a crucial component of the modern packaging industry. Despite the hydrophobicity and porosity of the base paper making it unsuitable for packaging purposes, a coating with specific properties is applied to impart hydrophobic and oleophobic characteristics. These papers, derived from plant fibers, are light, flexible, recyclable, and compostable materials. Since they are derived from renewable resources they are compatible to environment. Consequently, these papers have become indispensable in the area of packaging, embodying the industry’s commitment to both efficiency and sustainability.

In the preparation of oil and grease-resistant papers, surface properties such as contact angle, sliding angle, surface tension, and surface energy play a crucial role. Therefore, the success of the packaging and container industries lies in how efficiently one can apply these surface properties to produce papers with the desired characteristics.

We use the following surface properties to understand the behavior of Packaging and Containers products and improve their quality.

Chapitre 2 : Mesure de l’angle de contact

L’angle de contact quantifie la mouillabilité d’une surface en représentant l’angle entre la surface d’un liquide et une surface solide.
Recherche Dropletlab

Sample Image taken from Droplet Lab Tensiometer.

Young – Méthode Laplace

Méthode polynomiale

Angle de contact dynamique

Ideally, when we place a drop on a solid surface, a unique angle exists between the liquid and the solid surface. We can calculate the value of this ideal contact angle (the so-called Young’s contact angle) using Young’s equation. In practice, due to surface geometry, roughness, heterogeneity, contamination, and deformation, the contact angle value on a surface is not necessarily a single consistent value but rather falls within a range. The upper and lower limits of this range are known as the advancing and receding contact angles, respectively. The values of advancing and receding contact angles for a solid surface are highly sensitive to many parameters, such as temperature, humidity, homogeneity, and minor contamination of the surface and liquid. For example, the advancing and receding contact angles of a surface can differ at different locations.

Angle de contact dynamique par rapport à l’angle de contact statique

Les surfaces et les revêtements pratiques présentent naturellement une hystérésis d’angle de contact, indiquant une gamme de valeurs d’équilibre. Lorsque nous mesurons les angles de contact statiques, nous obtenons une seule valeur dans cette plage. S’appuyer uniquement sur des mesures statiques pose des problèmes, tels qu’une mauvaise répétabilité et une évaluation incomplète de la surface en ce qui concerne l’adhérence, la propreté, la rugosité et l’homogénéité.

In practical applications, we need to understand how easily a liquid spreads (advancing angle) and how easily it is removed (receding angle), such as in painting and cleaning. Measuring advancing and receding angles offers a holistic view of liquid-solid interaction, unlike static measurements, which yield an arbitrary value within the range.

Ces informations sont cruciales pour les surfaces du monde réel avec des variations, une rugosité et une dynamique, aidant des industries telles que les cosmétiques, la science des matériaux et la biotechnologie à concevoir des surfaces efficaces et à optimiser les processus.

Découvrez comment la mesure de l’angle de contact est effectuée sur notre tensiomètre

Pour une compréhension plus complète de la mesure de l’angle de contact, lisez notre mesure de l’angle de contact : le guide définitif

Open Benchmark Data: Contact Angle & Surface Energy

These reference measurements show how deionized water wets four standard substrates measured with the Droplet Lab Dropometer. Use them as visual and numerical benchmarks when you're checking your own sample preparation, treatments, and chemistry.

Full contact angle and surface energy datasets (including additional liquids and statistics) are available on our dataset hub.

Glass - DI Water
Glass - DI Water
Nylon - DI Water
Nylon - DI Water
PMMA - DI Water
PMMA - DI Water
Teflon - DI Water
Teflon - DI Water

The droplet images above are taken from the same benchmark series as our open dataset. For each substrate and probe liquid we report:

● Advancing and receding contact angles (and hysteresis)
● Derived surface energy (SFE) values based on multi-liquid measurements
● Measurement conditions, uncertainties, and sample preparation details

Comparing your own droplet shapes and angles against these references is a fast way to spot contamination, treatment drift, or unexpected changes in wettability.

Chapitre 3 : Mesure de la tension superficielle

Cette propriété mesure la force qui agit à la surface d’un liquide, dans le but de minimiser sa surface.

Mesure de la tension superficielle

Sample Image taken from Droplet Lab Tensiometer

Tension superficielle dynamique

La tension superficielle dynamique diffère de la tension superficielle statique, qui fait référence à l’énergie de surface par unité de surface (ou à la force agissant par unité de longueur le long du bord d’une surface liquide).

La tension superficielle statique caractérise l’état d’équilibre de l’interface liquide, tandis que la tension superficielle dynamique tient compte de la cinétique des changements à l’interface. Ces changements peuvent impliquer la présence de tensioactifs, d’additifs ou de variations de température, de pression et de composition à l’interface.

Quand utiliser la mesure dynamique de la tension superficielle

Dynamic surface tension is essential for processes that involve rapid changes at the liquid-gas or liquid-liquid interface, such as droplet and bubble formation, coalescence (change in surface area), the behavior of foams, and the drying of paints (change in composition, e.g., evaporation of solvent). It is measured by analyzing the shape of a hanging droplet over time.

La tension superficielle dynamique s’applique à diverses industries, notamment les cosmétiques, les revêtements, les produits pharmaceutiques, la peinture, l’alimentation et les boissons, ainsi que les processus industriels, où la compréhension et le contrôle du comportement des interfaces liquides sont essentiels pour la qualité du produit et l’efficacité des processus.

Apprenez comment la mesure de la tension superficielle est effectuée sur notre tensiomètre

Pour une compréhension plus complète de la mesure de l’énergie de surface, lisez notre mesure de la tension superficielle : le guide définitif

Chapitre 4 : Mesure de l’énergie de surface

L’énergie de surface fait référence à l’énergie nécessaire pour créer une unité de surface d’une nouvelle surface.
231

Sample Image taken from Droplet Lab Tensiometer

Découvrez comment la mesure de l’énergie de surface est effectuée sur notre tensiomètre

Pour une compréhension plus complète de la mesure de l’énergie de surface, lisez notre mesure de l’énergie de surface : le guide définitif

For benchmark contact angle and surface energy values on glass, nylon, PMMA, and Teflon, see the Open Benchmark Data panel above or visit our Dataset Hub for full CSV downloads.

Chapitre 5 : Mesure de l’angle de glissement

L’angle de glissement mesure l’angle auquel un film liquide glisse sur une surface solide. Il est couramment utilisé pour évaluer la résistance au glissement d’une surface.

Angle de glissement 1

Sample Image taken from Droplet Lab Tensiometer

Apprenez comment la mesure de l’angle de glissement est effectuée sur notre tensiomètre

Pour une compréhension plus complète de la mesure de l’angle de glissement, lisez notre Mesure de l’angle de glissement : le guide définitif

Chapitre 6 : Applications dans le monde réel

Within the Packaging and Containers industry, several case studies exemplify the advantages of conducting surface property measurements.

Soyhull-Derived Biodegradable Packaging Films: Using Water Contact Angle to Quantify Surface Wettability and Moisture Sensitivity

Due to their inability to biodegrade, petroleum-based plastics pose significant environmental challenges by disrupting aquatic, marine, and terrestrial ecosystems. Additionally, the widespread presence of microplastics and nanoplastics induces serious health risks for humans and animals. These pressing issues create an urgent need for designing and developing eco-friendly, biodegradable, renewable, and non-toxic plastic alternatives. To this end, agro-industrial byproducts such as soyhulls, which contain 29–50% lignocellulosic residue, are handy. This study extracted lignocellulosic residue from soyhulls using alkali treatment, dissolved it in ZnCl2 solution, and crosslinked it with calcium ions and glycerol to create biodegradable films. The film formulation was optimized using the Box–Behnken design, with response to tensile strength (TS), elongation at break (EB), and water vapor permeability (WVP). The optimized films were further characterized for color, light transmittance, UV-blocking capacity, water absorption, contact angle, and biodegradability. The resulting optimized film demonstrated a tensile strength of 10.4 ± 1.0 MPa, an elongation at break of 9.4 ± 1.8%, and a WVP of 3.5 ± 0.4 × 10−11 g·m−1·s−1·Pa−1. Importantly, 90% of the film degrades within 37 days at 24% soil moisture. This outcome underscores the potential of soyhull-derived films as a sustainable, innovative alternative to plastic packaging, contributing to the circular economy and generating additional income for farmers and allied industries.

Role of the Droplet Lab Goniometer

The authors used a Droplet Lab Dropometer to measure water contact angle (WCA) on the optimized soyhull-extract (SHE) film—directly quantifying the film’s surface wetting behavior (hydrophilicity/hydrophobicity), which is central to packaging performance where moisture exposure, surface interactions, and barrier behavior matter. The paper explicitly reports that WCA was measured using a Dropometer (Droplet Lab, Markham, ON, Canada) and evaluated over time (0, 10, 20, 30 s) to observe changes after droplet placement.

Key Findings

  • Optimized packaging film performance: The optimized film achieved TS = 10.4 ± 1.0 MPa, EB = 9.4 ± 1.8%, and WVP = 3.5 ± 0.4 × 10−11 g·m−1·s−1·Pa−1.
  • Validated optimization approach: Predicted vs. experimental TS/EB/WVP were statistically consistent (no significant differences reported).
  • Surface wettability quantified by Dropometer: The film surface is hydrophilic (WCA < 90°) and WCA decreased from ~76.9° (0 s) to ~49.2° (30 s), indicating increasing wetting/spreading/interaction with water over time.
  • Relevance vs conventional plastics: The authors note LDPE is more hydrophobic (reported WCA ~100.7°), and they discuss pathways (e.g., incorporating hydrophobic components like lignin/waxes) to improve water resistance.

End-of-life advantage: The film shows rapid biodegradation (reported ~90% degradation within 37 days at 24% soil moisture in the abstract).

Why It Matters

For packaging teams developing bio-based film structures, contact angle is a fast, quantitative way to screen whether a new film will behave more like a moisture-sensitive, hydrophilic biopolymer (potentially needing coatings/lamination) versus a more water-repellent packaging surface. Here, the Dropometer WCA time-series reveals that the soyhull-derived film wets increasingly over 30 seconds—information that can directly inform coating selection, surface treatments, and QC specs when targeting real-world humidity/water exposure while still benefiting from strong biodegradability and sustainability claims.

Method Snapshot

Optimized soyhull-extract (SHE) biodegradable film; sessile water droplet contact angle measured with a Droplet Lab Dropometer (0.05 µL precision dropper) and analyzed with sessile-drop software; WCA tracked at 0/10/20/30 s after droplet placement (static sessile-drop measurement; exact test temperature and liquid surface tension not reported).

Data Note

  • Time-resolved contact-angle measurements at 0, 10, 20, and 30 seconds and reported angles (76.9°, 58.3°, 52.7°, 49.2°) illustrating increased hydrophilicity over time
Figure

Citation (APA Format)

Regmi, S., Paudel, S., & Janaswamy, S. (2024). Development of eco-friendly packaging films from soyhull lignocellulose: Towards valorizing agro-industrial byproducts. Foods, 13(24), 4000. https://doi.org/10.3390/foods13244000

View Publication →

Loss of Package Sterility due to Leaker Formation

Défi: The sterility of aseptic packages can be compromised during storage and distribution due to rough or improper handling.

Solution: In one study, scientists focused on determining the threshold pressure required to create a leak. They observed significantly lower threshold pressures in the case of low surface tension liquids, such as safranin red dye, compared to high surface tension liquids, like distilled water. This insight allows manufacturers to proactively avoid conditions that could lead to leakage issues. A tensiometer like Droplet Lab's Dropometer precisely measures surface tension, enabling manufacturers to identify and understand how different liquids interact with packaging materials. By providing accurate data on surface tension, it helps in assessing the susceptibility of packaging to leaks and supports the development of more robust packaging solutions, thus maintaining package sterility.

Loss of Package Sterility due to Leaker Formation

Removal of Printing Ink in Mechanical Recycling Process

Défi : Printing ink in flexible packaging materials can cause contamination in the mechanical recycling process.

Solution : The removal of printing ink residue from the surface of flexible plastic packaging can be achieved through detergency, mechanical, and chemical cleaning processes. In this context, contact angle measurements are invaluable for studying the interaction between the polymer and surfactant. These measurements are highly effective in comparing the wetting behavior of surfactants on various printing ink systems and non-printed film surfaces.

Removal of Printing Ink in Mechanical Recycling Process

Improving Label Adhesion on Curved Surfaces

Défi : There was a big issue with label adhesion in packages that have curved surfaces, resulting in peeling and poor aesthetics.

Solution : The manufacturer applied the surface tension measurements that helped in the selection of label materials with appropriate adhesive properties for curved surfaces. These optimized properties of adhesives ensured strong and lasting label adhesion, enhancing the overall visual appeal of the packaging.

Improving Label Adhesion on Curved Surfaces

Nous sommes vos partenaires dans la résolution de votre activité et de votre Défis

Si vous êtes intéressé par la mise en œuvre de ces applications ou de toute autre application, veuillez nous contacter.

Chapitre 7 : Normes et lignes directrices

In an industry where precision reigns supreme, how can Packaging and Containers manufacturers ensure their products withstand scrutiny? The answer lies in standards and guidelines: the compass that guides them through the complex maze of quality and performance.

TAPPI T 458 — Surface Wettability of Paper (Angle-of-Contact Method) / ASTM D724

What it is

A standardized sessile-drop contact angle method for porous paper/paperboard surfaces that quantifies resistance to wetting at a defined early time and how that apparent wettability changes over time. It’s commonly used as a practical, time-stamped wettability/absorption index for sizing control and process runnability.

When to use it

Sizing / holdout QC for printing, converting, and aqueous coating

Use fixed-time angles to detect lot-to-lot or roll-to-roll drift before it becomes press/coater waste.

Non-uniformity troubleshooting (directional + sidedness)

Use MD vs CD and wire vs felt sampling to identify where wetting/penetration behavior differs across the web.

In-scope / Out-of-scope

In scope
  • Porous paper and paperboard grades where wetting and penetration occur simultaneously.
  • Sessile-drop contact angle measured at defined timestamps (fixed-time reporting).
  • Initial + time-evolution reporting (early-time angle plus later-time angle and/or a rate-of-change indicator).
  • Controlled sample conditioning/environment per lab SOP (commonly aligned to standard paper conditioning atmospheres).
Out of scope
  • Universal “good/bad” cutoffs that transfer across different porous grades without site/grade calibration.
  • Mass-based absorbency / water uptake (use Cobb / TAPPI T 441 or similar when you need absorption by mass).
  • Advancing/receding angles, hysteresis, or dynamic surface tension characterization requirements.
  • Cases where the drop fully absorbs before the required timestamp: report as “not measurable at X s” rather than forcing a number (use a separate early-time/high-speed internal metric if needed).

Minimum you must report (checklist)

  • Substrate description: grade/structure, basis weight (or caliper), sizing/coating type if known, and side + orientation (wire/felt; MD/CD) where applicable.
  • Conditioning conditions: temperature/RH (and conditioning time/atmosphere).
  • Test liquid(s): identity (DI water baseline if used) and liquid temperature (if controlled).
  • Drop volume + dispense details: volume, delivery method (needle/tip), and any height/placement controls.
  • Defined timestamps: the exact capture times (e.g., 5 s and 60 s) and how “time zero” is set (e.g., first frame after dispense).
  • Reported metrics: θ@5s, θ@60s, and Δθ(5→60s) (or your defined change metric).
  • Replicates + statistics: replicate count per zone and summary statistic (median or mean) plus variability (IQR or SD).
  • Data-quality rules: exclusion criteria (distorted footprint/failed edge detection, sheet not flat/secured, drop disappears early) and how exclusions are recorded.

On porous sheets the apparent contact angle is time-dependent due to simultaneous wetting and penetration, so angles without a timestamp are not comparable. Automating fixed-time capture improves repeatability, but pass/fail limits must be calibrated per grade family against real print/coating/converting outcomes.

How to interpret results (guardrails)

  • Only compare like-for-like: same liquid, drop volume, conditioning, optics/settings, and timestamps—treat angles as protocol-specific indices, not universal constants.
  • θ@5s (early-time index): lower values generally indicate faster early wetting (less resistance/holdout), while higher values indicate more early-time resistance under that SOP.
  • Δθ(5→60s) (change-over-time index): a larger magnitude drop in angle typically signals faster evolution (often penetration/absorption-dominated on porous sheets), but confirm root cause with complementary process/context data when needed.
  • Variability and deltas are actionable signals: spikes in IQR/SD, strong MD–CD differences, or wire–felt differences often predict non-uniform converting/printing behavior even when the overall median looks “on target.”

Maintenant, c’est à votre tour

We hope this guide showed you how to apply surface science in the Packaging and Containers industry.

Maintenant, nous aimerions vous céder la parole :

Feel free to leave a comment below—we’d love to hear from you.

Laisser une réponse

Votre adresse e-mail ne sera pas publiée. Les champs obligatoires sont marqués *